Search results for "Fuel Cell"
showing 10 items of 260 documents
Impact of Ir modification on the durability of FeNC catalysts under start-up and shutdown cycle conditions
2022
A common problem associated with FeNC catalysts is their poor stability dominated by the carbon oxidation reaction (COR). In this work, the feasibility of stabilizing FeNC catalysts with small quantities of Ir was explored. With iridium being present, instead of COR the oxygen evolution reaction should be favored. The impact on structure and morphology was investigated by 57Fe Mössbauer spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and transmission electron microscopy. The catalytic activity and durability for the oxygen reduction reaction was evaluated by rotating ring disc electrode experiments and accelerated stress tests mimicking the start-up and shutdown cycle (SS…
Simulation analysis of fuel cell integration in a hybrid car
2019
Abstract Fuel cell is one of the green technologies that can help reduce toxic gas and decreasing effect of greenhouse gases in the world. This paper attempts to improve simulation model of fuel cell system that is easy to use and at the same time have an acceptable accuracy. The simulation model is developed through Matlab/Simulink software using Energetic Macroscopic Representation method which accuracy is compared with an established model. Simulation analysis of fuel cell integration is conducted by using experimental data from a real hybrid car. There are two potential types of system that were considered for the hybrid car in term of electricity generation and power produced to move t…
Direct electricity production from Avgas UL91 fuel
2016
As fuel for fuel cells can be used various substances, but generally fuel cells are powered by hydrogen. However, problems with the storage of hydrogen are the reason for the search of new fuels for fuel cells. The paper presents the possibility of using Avgas fuel as fuel for fuel cell. The Avgas does not have the feature of electrical conductivity, for this reason a detergent (nonionic surfactant) was used for dissolving fuel in an electrolyte. The work shows possible electrooxidation of Avgas fuel emulsion prepared on the basis of a nonionic surfactant on a platinum electrode in an aqueous solution of H2SO4. As non-ionic surfactant was used the detergent Syntanol DS-10. The emulsion was …
Electrochemical Processes and Apparatuses for the Abatement of Acid Orange 7 in Water
2014
We have studied the electrochemical treatment of aqu eous solutions contaminated by Acid Orange 7 (AO7) by electro-Fenton process (EF). The main object ive was to evaluate how the electrochemical route affects the performances of the d egradation process. EF process was carried out in a number of very different reactors: conventional bench scale electrochem ical cell, microfluidic electrochemical reactor, microbial fuel cell and stack for reverse electrodialysis processes. The utilisation of micro devices allowed to work without the addition of a supporting elec trolyte and improved the performances of EF. Microbial fuel cell did not need the supply of electric energy bu t our device requir…
Ab initio thermodynamic study of (Ba,Sr)(Co,Fe)O3 perovskite solid solutions for fuel cell applications
2013
(Ba,Sr)(Co,Fe)O3 (BSCF) perovskite solid solutions are promising materials for solid oxide fuel cell cathodes and oxygen permeation membranes. Cathode performance strongly depends on the morphology of these materials remaining as a single phase or two-phase mixture. Combining ab initio calculations of the atomic and electronic structure of different supercells with thermodynamics of solid solutions, we have constructed and discussed phase diagrams of several important BSCF chemical compositions. It is demonstrated that in BSC cobaltite solid solution the spinodal decomposition may occur already at relatively low temperatures, while ferrite (BSF and SCF) solid solutions decompose at relative…
Possibility of using NiCO2O4 alloy as catalyst for fuel electrode of hydrazine fuel cell
2016
The work presents a possibility of the use of NiCo2O4 alloys as catalysts for electrooxidation of hydrazine. The research was done by the method of polarizing cuvers of electrooxidation of hydrazine in glass vessel in aqueous solution of KOH, on electrode with NiCo2O4 alloy as a catalyst. Conducted measurements show that there is a possibility of electrooxidation of hydrazine on NiCo2O4 electrode. The current density is low, but the price of the catalyst is much lower than platinum.
Possibility of fuel cell powering with grape seed oil
2015
In the last few years alternative energy sources have been fast developing. One of technical device using these sources is fuel cell. Fuel cell performs direct conversion of chemical fuel into electrical energy, without combustion and characterized by high efficiency. Most commonly fuel cells are powered by hydrogen. However, problems with the storage of hydrogen are the reason for the search of new fuels for fuel cells. Due to development of the renewable energy sources, the powering of high efficiency power sources with bio-fuels is very important. Vegetable oil is an alternative fuel for Diesel engines and for heating oil burners. Powering high efficiency power sources (like fuel cells) …
Y:BaZrO 3 Perovskite Compounds II: Designing Protonic Conduction by using MD Models
2011
The proton dynamics in Y-doped BaZrO(3) derivatives, in particular the different dopant environments within a Pm3m cubic framework, were studied by using classical molecular dynamics (MD) calculations. Single- and double substitution of zirconium by yttrium atoms was considered. The presence of yttrium induced variations in the surrounding oxygen sites, according to their local geometrical arrangements. The differences among such distinct oxygen sites became evident when protons interacted with them and upon changes in the temperature. So, different proton transfer pathways, which had different energy barriers, characterized the topologically different oxygen sites. The experimental proton-…
Different scenarios of electric mobility: Current situation and possible future developments of fuel cell vehicles in Italy
2020
The diffusion of electric vehicles in Italy has started but some complications weight its spread. At present, hybrid technology is the most followed by users, due particularly to socioeconomic factors such as cost of investment and range anxiety. After a deep discussion of the Italian scenario, the aim of the paper is to recognize whether fuel cell technology may be an enabling solution to overcome pollution problems and respect for the environment. The opportunity to use fuel cells to store electric energy is quite fascinating&mdash
Fuel Cell Performances of Bio-Membranes Made of Chitosan-Polyelectrolyte Thin Films and Nanowires into Anodic Alumina Membranes
2012
Chitosan (CS) / Phosphotungstic acid (PTA) polyelectrolytes in the shape of thin films and nanowires supported by Anodic Alumina Membranes (AAM) have been fabricated through solution cast and filtration techniques, respectively. Their ability to function in a H2/O2 fuel cell under mild conditions (room temperature, low humidity and low Pt loading) is proved for the first time. The fabricated membrane electrode assemblies produce power peaks of ~20 mW cm-2 for both films and nanowires. The CS/PTA films (20-40 μm thick) are able to produce a quite constant power density of ~10 mW cm-2 recorded for at least 7 h. The gradual decrease of the power output with time observed for CS/PTA nanowires i…